The cationic Cu(I) complex [Cu(N^N)2]+, where N^N is bis(indazol-1-yl)phenylmethane, was synthesized as chloride or tetrafluoroborate salt by reacting CuCl or [Cu(NCCH3)4][BF4] with bis(indazol-1-yl)phenylmethane under mild conditions. The structure of [Cu(N^N)2]Cl was ascertained by single-crystal X-ray diffraction. The complex exhibited bright yellow emission upon excitation with near UV and violet light, attributed to triplet LLCT/MLCT transitions on the basis of experimental data and computational outcomes.
Autori: | ||
Data di pubblicazione: | 2020 | |
Titolo: | Luminescent Cu(I) complex with bis(indazol-1-yl)phenylmethane as chelating ligand | |
Rivista: | INORGANIC CHEMISTRY COMMUNICATIONS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.inoche.2020.107894 | |
Volume: | 116 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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