Abstract: This paper describes the preparation, broad characterization and study of activity in hydrogenation and hydroformylation reactions of an easily produced 0.18% Rh/Al2O3. Analytical studies on fresh and recycled samples shed light on the smart properties of such catalyst. Results showed high activity as well as fine/excellent chemoselectivity or regioselectivity, characteristics that may suggest a wide range of applicability. Graphic Abstract: The low metal content catalyst 0.18% Rh/Al2O3 was very active in both hydrogenation and hydroformylation reactions so providing intermediates for valuable APIs, as Nabumetone and Eletriptan, and a fragrance with a fresh, green-floral smell, that recalls scent of lily of the valley.[Figure not available: see fulltext.]
Autori: | Piccolo O. (Corresponding) | |
Data di pubblicazione: | 2020 | |
Titolo: | A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions | |
Rivista: | CATALYSIS LETTERS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s10562-020-03407-5 | |
Volume: | 150 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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File | Descrizione | Tipologia | Licenza | |
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ALowRhodiumContentSmartCatalys.pdf | Documento in Pre-print | Accesso libero (no vincoli) | Open Access Visualizza/Apri |