Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) by Humicola insolens (HiC) and Thermobifida cellulosilytica (Cut) cutinases is investigated. For the first time, the different depolymerization mechanisms of PBTF (endo-wise scission) and PBF (exo-wise cleavage) has been unveiled and correlated to the chemical structure of the two polyesters.
Autori: | ||
Data di pubblicazione: | 2019 | |
Titolo: | Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms | |
Rivista: | ENVIRONMENT INTERNATIONAL | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.envint.2019.05.046 | |
Volume: | 130 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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