The Cu(I) coordination polymer [Cu3(μ3-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.
Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands
Bortoluzzi M.;Enrichi F.;Vomiero A.
2019-01-01
Abstract
The Cu(I) coordination polymer [Cu3(μ3-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
2019-ICC-Cu.pdf
non disponibili
Descrizione: articolo
Tipologia:
Versione dell'editore
Licenza:
Accesso chiuso-personale
Dimensione
1.18 MB
Formato
Adobe PDF
|
1.18 MB | Adobe PDF | Visualizza/Apri |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
