A new bio-generated rhodium based system embedded in a peculiar polysaccharide matrix (Rh-EPS), was obtained and purified from cultures of bacterial cells of Klebsiella oxytoca DSM 29614. The product was analyzed with different techniques to obtain information on its structure-property correlation. In order to determine its catalytic activity and selectivity in the aqueous biphasic hydroformylation some olefins were chosen as model substrates, obtaining fine-good results.
A new bio-generated rhodium based system embedded in a peculiar polysaccharide matrix (Rh-EPS), was obtained and purified from cultures of bacterial cells of Klebsiella oxytoca DSM 29614. The product was analyzed with different techniques to obtain information on its structure-property correlation. In order to determine its catalytic activity and selectivity in the aqueous biphasic hydroformylation some olefins were chosen as model substrates, obtaining fine-good results.
Autori: | ||
Data di pubblicazione: | 2015 | |
Titolo: | A new biogenerated Rh-based catalyst for aqueous biphasic hydroformylation | |
Rivista: | CATALYSIS COMMUNICATIONS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.catcom.2015.08.001 | |
Volume: | 71 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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Reprint Rh-EPS.pdf | Versione dell'editore | Accesso gratuito (solo visione) | Open Access Visualizza/Apri |