Manganese and iron 2,6-disubstituted meso-tetraphenylporphyrins, bearing halogen atoms on the β-positions, have been used as catalysts for the oxidation of a cardanol derivative (hydrogenated tertbutylcardanol), using iodosilbenzene or hydrogen peroxide as oxygen atom donors. The reaction products can be correlated to the catalyst structure and to the nature of the oxidants. © 2002 Society of Porphyrins & Phthalocyanines.
Manganese and iron tetraphenylporphyrin-catalyzed oxidation of a cardanol derivative (hydrogenated tert-butylcardanol)
Crestini C.;Neri V.;
2002-01-01
Abstract
Manganese and iron 2,6-disubstituted meso-tetraphenylporphyrins, bearing halogen atoms on the β-positions, have been used as catalysts for the oxidation of a cardanol derivative (hydrogenated tertbutylcardanol), using iodosilbenzene or hydrogen peroxide as oxygen atom donors. The reaction products can be correlated to the catalyst structure and to the nature of the oxidants. © 2002 Society of Porphyrins & Phthalocyanines.
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