A neutral hexacoordinate Si(IV) complex containing two tridentate Nheterocyclic carbene ligands is synthesised and characterized by Xray crystallography, optical spectroscopy, electrochemistry and computational methods. The stable compound exhibits remarkable deep-blue photoluminescence particularly in the solid state that enables its use as electroluminescent material in organic lightemitting diodes.
A stable and true-blue emissive hexacoordinate Si(IV) N-heterocyclic carbene complex and its use in organic light-emitting diodes
Polo, Federico;
2024-01-01
Abstract
A neutral hexacoordinate Si(IV) complex containing two tridentate Nheterocyclic carbene ligands is synthesised and characterized by Xray crystallography, optical spectroscopy, electrochemistry and computational methods. The stable compound exhibits remarkable deep-blue photoluminescence particularly in the solid state that enables its use as electroluminescent material in organic lightemitting diodes.
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