Polycrystalline X-type hexagonal ferrites are investigated regarding phase formation at different temperatures and the effect of partial substitution of Ga3+ for Fe3+ ions in the octahedral and tetrahedral sites of the unit cell. The system of Sr2Co2GaxFe28−xO46 (x ranges from 0.0 to 2.0 in steps of 0.4) was synthesised by the sol–gel auto-combustion technique and calcined between 1200–1300 °C with a temperature of 1300 °C required to be able to obtain a pure X-phase. Lattice parameter a did not alter with partial substitution, suggesting minimum crystal distortion, while the unit cell volume shrank from 2488 to 2465 Å3 due to smaller size of Ga3+. Denser and more agglomerated grains were observed in the samples heated to 1300 °C. Soft magnetic behaviour was seen in all samples and the saturation magnetisation was 63–69 A m2 kg−1 for pure X-ferrites, with low coercivity between 8.5–9.5 kA m−1 (106–119 Oe). Reasonably high Ha and K1 values were observed due to a cone of magnetisation partially aligned along the c-axis, and lower HC, Ha and K1 values were seen for pure X-ferrites, decreasing monotonously with increasing gallium substitution. dM/dH curves for pure X-ferrites indicated one magnetic domain type with restricted domain dispersion, and superior exchange coupling with more gallium substitution. Mössbauer spectroscopy of samples heated to 1300 °C reveals Fe3+ ions in high spin state and probable occupancy of Ga3+ in the octahedral site a = a1+a2. Room temperature (RT) dielectric studies show a significant rise in dielectric constant at low frequencies <50 Hz and in ac conductivity with increasing gallium.

Gallium-substituted X-type hexagonal ferrites Sr2Co2GaxFe28−xO46: effect of substitution and heating temperature on phase formation and magnetic and dielectric properties

Pullar, Robert C.;
2023-01-01

Abstract

Polycrystalline X-type hexagonal ferrites are investigated regarding phase formation at different temperatures and the effect of partial substitution of Ga3+ for Fe3+ ions in the octahedral and tetrahedral sites of the unit cell. The system of Sr2Co2GaxFe28−xO46 (x ranges from 0.0 to 2.0 in steps of 0.4) was synthesised by the sol–gel auto-combustion technique and calcined between 1200–1300 °C with a temperature of 1300 °C required to be able to obtain a pure X-phase. Lattice parameter a did not alter with partial substitution, suggesting minimum crystal distortion, while the unit cell volume shrank from 2488 to 2465 Å3 due to smaller size of Ga3+. Denser and more agglomerated grains were observed in the samples heated to 1300 °C. Soft magnetic behaviour was seen in all samples and the saturation magnetisation was 63–69 A m2 kg−1 for pure X-ferrites, with low coercivity between 8.5–9.5 kA m−1 (106–119 Oe). Reasonably high Ha and K1 values were observed due to a cone of magnetisation partially aligned along the c-axis, and lower HC, Ha and K1 values were seen for pure X-ferrites, decreasing monotonously with increasing gallium substitution. dM/dH curves for pure X-ferrites indicated one magnetic domain type with restricted domain dispersion, and superior exchange coupling with more gallium substitution. Mössbauer spectroscopy of samples heated to 1300 °C reveals Fe3+ ions in high spin state and probable occupancy of Ga3+ in the octahedral site a = a1+a2. Room temperature (RT) dielectric studies show a significant rise in dielectric constant at low frequencies <50 Hz and in ac conductivity with increasing gallium.
File in questo prodotto:
File Dimensione Formato  
11JMatChemC15035.pdf

non disponibili

Tipologia: Versione dell'editore
Licenza: Accesso chiuso-personale
Dimensione 6.38 MB
Formato Adobe PDF
6.38 MB Adobe PDF   Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/5043340
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 1
social impact