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EnglishA hundred-fold substrate selectivity was observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes from C4 to C10 in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as the surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed.
A hundred-fold substrate selectivity was observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes from C4 to C10 in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as the surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. Something in the water: A hundred-fold substrate selectivity is observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes (C4-C10) in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as a surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Autori: | ||
| Data di pubblicazione: | 2014 | |
| Titolo: | Surfactant-Induced Substrate Selectivity in the Palladium-Nanoparticle-Mediated Chemoselective Hydrogenation of Unsaturated Aldehydes in Water | |
| Rivista: | CHEMCATCHEM | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/cctc.201402034 | |
| Volume: | 6 | |
| Appare nelle tipologie: | 2.1 Articolo su rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| ChemCatChem 2014.pdf | Documento in Post-print | Accesso chiuso-personale | Open Access Visualizza/Apri |
http://hdl.handle.net/10278/42429
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