A hundred-fold substrate selectivity was observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes from C4 to C10 in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as the surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed.

A hundred-fold substrate selectivity was observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes from C4 to C10 in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as the surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. Something in the water: A hundred-fold substrate selectivity is observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes (C4-C10) in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as a surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Surfactant-Induced Substrate Selectivity in the Palladium-Nanoparticle-Mediated Chemoselective Hydrogenation of Unsaturated Aldehydes in Water

LA SORELLA, GIORGIO;CANTON, Patrizia;STRUKUL, Giorgio;SCARSO, Alessandro
2014-01-01

Abstract

A hundred-fold substrate selectivity was observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes from C4 to C10 in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as the surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. Something in the water: A hundred-fold substrate selectivity is observed in the competitive chemoselective hydrogenation of seven α,β-unsaturated aldehydes (C4-C10) in water with palladium nanoparticles stabilized by sodium dodecyl sulfonate as a surfactant. The medium makes the longer lipophilic substrates hundreds of times more reactive than the shorter more hydrophilic ones, whereas in an organic medium almost no difference is observed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
2014
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/42429
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