Reaction of CH2-acidic nucleophiles with nitrogen mustard carbonate analogue led to a new synthetic procedure for substituted piperidines. Phenylsulphonyl acetonitrile and malononitrile were used as substrates resulting in the related substituted piperidines. A reaction mechanism has been proposed and discussed.
Synthesis of piperidine derivates employing a nitrogen mustard carbonate analogue
ARICO', Fabio;TUNDO, Pietro
2013-01-01
Abstract
Reaction of CH2-acidic nucleophiles with nitrogen mustard carbonate analogue led to a new synthetic procedure for substituted piperidines. Phenylsulphonyl acetonitrile and malononitrile were used as substrates resulting in the related substituted piperidines. A reaction mechanism has been proposed and discussed.
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43. Acta Manilana 2014.pdf
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