The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the iminium salt [(PhCH2) 2N=CHPh][WCl6], 1, and the ammonium one [tbaH][WCl 6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects. © 2014 American Chemical Society.
The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the iminium salt [(PhCH2)2N CHPh][WCl6], 1, and the ammonium one [tbaH][WCl6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects.
Tribenzylamine C−H Activation and Intermolecular Hydrogen Transfer Promoted by WCl6
BORTOLUZZI, Marco;
2014-01-01
Abstract
The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the iminium salt [(PhCH2)2N CHPh][WCl6], 1, and the ammonium one [tbaH][WCl6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects.
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