Selectivity and product distribution of hydrodechlorination (HDCl) of dieldrin and DDT are studied in different liquid phase systems, namely in: (1) in ethanol; and (2) in the supported ionic liquid heterogeneous catalytic system (multiphase system), composed by the organic phase and aqueous KOH, a quaternary ammonium ionic liquid promoter (Aliquat 336), and a metal catalyst, e.g. 5% Pd/C, 5% Pt/C, or Raney-Ni. At 50 8C and atmospheric pressure of hydrogen, a quantitative hydrodechlorination of DDT in the biphasic system with ionic liquid layer is achieved in 40 min and in 4 h with Raney-Ni and Pd/C, respectively, while the reaction on Pt/C or on Pd/C without Aliquat 336 is slow. Dieldrin undergoes partial dechlorination, with high selectivity achievable only for its mono- and bi-dechlorination products. Dechlorination pathways and reactivity of different types of organic chlorine atoms versus the catalyst nature and other conditions are discussed.
|Data di pubblicazione:||2005|
|Titolo:||Liquid Phase Hydrodechlorination of Dieldrin and DDT over Pd/C and Raney-Ni|
|Rivista:||APPLIED CATALYSIS. B, ENVIRONMENTAL|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/J.APCATB.2004.06.015|
|Appare nelle tipologie:||2.1 Articolo su rivista |