C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations

C-3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations. (C) 2019 Elsevier Ltd. All rights reserved.

Triphenylene based metal-pyridine cages

Giacomo Berton
Membro del Collaboration Group
;
LORENZETTO, TOMMASO
Membro del Collaboration Group
;
Giuseppe Borsato
Membro del Collaboration Group
;
Paolo Sgarbossa
Methodology
;
Claudio Santo
Investigation
;
Fabiano Visentin
Investigation
;
Fabrizio Fabris
Writing – Original Draft Preparation
;
Alessandro Scarso
Writing – Review & Editing
2019

Abstract

C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3719246
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