C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations
C-3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations. (C) 2019 Elsevier Ltd. All rights reserved.
Triphenylene based metal-pyridine cages
Giacomo BertonMembro del Collaboration Group
;LORENZETTO, TOMMASOMembro del Collaboration Group
;Giuseppe BorsatoMembro del Collaboration Group
;Paolo SgarbossaMethodology
;Claudio SantoInvestigation
;Fabiano VisentinInvestigation
;Fabrizio FabrisWriting – Original Draft Preparation
;Alessandro Scarso
Writing – Review & Editing
2019
Abstract
C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations
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