C3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations
C-3-symmetric pyridine containing tris-benzyl-O-substituted hexahydroxytriphenylene derivatives were prepared and used in combination with square-planar Pd(II) and Pt(II) complexes for the self-assembly of molecular cages in solution. The formation of a trigonal bipyramid M3L2 cage was demonstrated by multinuclear NMR analyses and pseudo 2D DOSY experiments and supported by semi-empirical calculations. (C) 2019 Elsevier Ltd. All rights reserved.
Autori: | |
Data di pubblicazione: | 2019 |
Titolo: | Triphenylene based metal-pyridine cages |
Rivista: | TETRAHEDRON LETTERS |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.tetlet.2019.151202 |
Volume: | 60 |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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