Unlike what was previously reported, the reaction of the hydrazine derivative [Ru(NH2NH2)2{P(OEt)3}4](BPh4)2 with p-tolyldiazonium tetrafluoroborate in CH2Cl2 afforded the boranehydrazine complex [RuCl(κ1-NH2NH2BPh3){P(OEt)3}4]BPh4. The complex was characterised spectroscopically (IR and NMR) and by X-ray crystal structure determination.

Preparation and crystal structure of the boranehydrazine complex [RuCl(κ1-NH2NH2BPh3){P(OEt)3}4]BPh4

Albertin G.
;
Antoniutti S.;Bortoluzzi M.;
2019

Abstract

Unlike what was previously reported, the reaction of the hydrazine derivative [Ru(NH2NH2)2{P(OEt)3}4](BPh4)2 with p-tolyldiazonium tetrafluoroborate in CH2Cl2 afforded the boranehydrazine complex [RuCl(κ1-NH2NH2BPh3){P(OEt)3}4]BPh4. The complex was characterised spectroscopically (IR and NMR) and by X-ray crystal structure determination.
File in questo prodotto:
File Dimensione Formato  
Preparation and crystal structure of th.pdf

non disponibili

Descrizione: pagina web
Tipologia: Altro materiale relativo al prodotto (file audio, video, ecc.)
Licenza: Accesso chiuso-personale
Dimensione 820.24 kB
Formato Adobe PDF
820.24 kB Adobe PDF   Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10278/3714813
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 0
  • ???jsp.display-item.citation.isi??? 0
social impact