ARCA è l'archivio istituzionale ad accesso aperto della ricerca dell'Università Ca' Foscari Venezia e nasce nel 2014 con lo scopo di raccogliere, diffondere e conservare la produzione scientifica dell'Università. Costituisce di fatto il catalogo della ricerca di Ateneo.
ARCA è un sistema Open Access: è non solo consultabile da tutti e visibile nei motori di ricerca, ma anche interoperabile con il portale cerCa. In questo modo vengono valorizzate la produzione scientifica dell'Ateneo e la visibilità dei ricercatori.

At 60-150 °C and 15-35 bar of H2, two model reactions of levulinic acid as the hydrogenation and the reductive amination with cyclohexylamine, were explored in a multiphase system composed of an aqueous solution of reactants, a hydrocarbon, and a commercial 5% Ru/C as a heterogenous catalyst. By tuning the relative volume of the immiscible water-hydrocarbon phases and the concentration of aq. solutions, a quantitative conversion of LA was achieved with formation of γ-valerolactone or N-cyclohexylmethyl pyrrolidone in >95% and 88% selectivity, respectively, while the catalyst was segregated in the hydrocarbon phase where it could be recycled in an effective semi-continuous protocol. Under such conditions, formic acid as an additive, affected the reactivity of LA through a competitive adsorption on the catalyst surface. This effect was crucial to improve selectivity for the reductive amination process. The comparison of 5% Ru/C to a series of carbon supports demonstrated that the segregation phenomenon in the hydrocarbon phase, never previously reported, was pH-dependent and effective for samples displaying a moderate surface acidity.

At 60-150 degrees C and 15-35 bar H-2, two model reactions of levulinic acid (LA), hydrogenation and reductive amination with cyclohexylamine, were explored in a multiphase system composed of an aqueous solution of reactants, a hydrocarbon, and commercial 5 % Ru/C as a heterogeneous catalyst. By tuning the relative volume of the immiscible water/hydrocarbon phases and the concentration of the aqueous solution, a quantitative conversion of LA was achieved with formation of gamma-valerolactone or N-(cyclohexylmethyl)pyrrolidone in >95 and 88 % selectivity, respectively. Additionally, the catalyst could be segregated in the hydrocarbon phase and recycled in an effective semi-continuous protocol. Under such conditions, formic acid additive affected the reactivity of LA through a competitive adsorption on the catalyst surface. This effect was crucial to improve selectivity for the reductive amination process. The comparison of 5 % Ru/C with a series of carbon supports demonstrated that the segregation phenomenon in the hydrocarbon phase, never previously reported, was pH-dependent and effective for samples displaying a moderate surface acidity.

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