Three phenolic model compounds representing bonding patterns of residual kraft lignin were incubated with manganese peroxidase from Lentinula edodes. Extensive degradation of all the phenolic models, mainly occurring via side-chain benzylic oxi- dation, was observed. Among the tested model compounds the diphenylmethane a-5 phenolic model was found to be the most reactive, yielding several products showing oxidation and fragmentation at the bridging position. The non-phenolic 5-50 biphenyl and 5-50 diphenylmethane models were found unreactive.
|Data di pubblicazione:||2000|
|Titolo:||The Reactivity of Phenolic and non-phenolic Residual Kraft Lignin Model Compounds with Mn (II)-Peroxidase from Lentinula edodes|
|Rivista:||BIOORGANIC & MEDICINAL CHEMISTRY|
|Appare nelle tipologie:||2.1 Articolo su rivista |
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