The present review highlights relevant recent examples (2013-2018) of sustainable synthetic reactions involving phosphorus and sulfur ylides. These examples include catalytic, halide- and base-free Wittig olefination reactions and P-ylides as CO2 activators. They also include sustainable protocols for the synthesis of S-ylides and recent applications of these C1 synthons as carbene precursors and in selected rearrangement reactions.
Greener and Sustainable Applications of Phosphorous and Sulfur Ylides
Giulia FioraniWriting – Original Draft Preparation
;Maurizio SelvaWriting – Review & Editing
;Alvise Perosa
Writing – Review & Editing
2018-01-01
Abstract
The present review highlights relevant recent examples (2013-2018) of sustainable synthetic reactions involving phosphorus and sulfur ylides. These examples include catalytic, halide- and base-free Wittig olefination reactions and P-ylides as CO2 activators. They also include sustainable protocols for the synthesis of S-ylides and recent applications of these C1 synthons as carbene precursors and in selected rearrangement reactions.
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Aldrichimica Acta 2018, 51, 63-75.pdf
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