A new catalytic synthesis of Cyclamen-aldehyde (3-(4-isopropylphenyl)-2-methylpropanal) has been developed. The devised synthetic approach entails as the key step the asymmetric hydrogenation of (E)-3-(4- isopropylphenyl)-2-methyl acrylic acid which has been carried out with ees of about 60% by using a catalytic system prepared by combining in situ [Ru(C6H6)Cl2]2 and (S)-MeO-BIPHEP.
Autori: | ||
Data di pubblicazione: | 2012 | |
Titolo: | Asymmetric catalysis in fragrance chemistry: a new catalytic approach to non racemic Cyclamen-aldehyde | |
Rivista: | SCIENCES AT CÀ FOSCARI | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.7361/SciCF-273 | |
Volume: | 1 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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