The high yielding synthesis of a novel benzocyclotrimer is herein presented. The syn-diastereomer is obtained as major product, presumably in virtue of the presence of an oxa-bridge of the bicylic components. The three oxa-bridges can be used for further functionalization, as well as the six bromine atoms of the three aromatic rings, as demonstrated in the aromatization of a mixture of anti-1 and syn-1 (3:7) leading to trinaphthylene.
|Titolo:||Highly diastereoselective synthesis of a novel functionalized benzocyclotrimer|
FABRIS, Fabrizio [Writing – Original Draft Preparation]
|Data di pubblicazione:||2018|
|Appare nelle tipologie:||2.1 Articolo su rivista |