A novel supramolecular cage built from the self-assembly of tris(2-pyridylmethyl)amine zinc complexes through imine condensation chemistry is reported. The cage recognition properties over a variety of structurally related guests, together with the kinetic study of the template assembly and disassembly, have been investigated in detail. This knowledge has been used to selectively modulate the rate of both assembly and disassembly processes. In particular, a novel disassembly method induced by strain release of the guest has been developed.
Triggering Assembly and Disassembly of a Supramolecular Cage
Badetti, Elena;Zonta, Cristiano
2017-01-01
Abstract
A novel supramolecular cage built from the self-assembly of tris(2-pyridylmethyl)amine zinc complexes through imine condensation chemistry is reported. The cage recognition properties over a variety of structurally related guests, together with the kinetic study of the template assembly and disassembly, have been investigated in detail. This knowledge has been used to selectively modulate the rate of both assembly and disassembly processes. In particular, a novel disassembly method induced by strain release of the guest has been developed.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
jacs 2017.pdf
non disponibili
Descrizione: full text
Tipologia:
Versione dell'editore
Licenza:
Accesso chiuso-personale
Dimensione
2.16 MB
Formato
Adobe PDF
|
2.16 MB | Adobe PDF | Visualizza/Apri |
FullJACS1204.pdf
accesso aperto
Descrizione: full text post-print dell'autore
Tipologia:
Documento in Post-print
Licenza:
Accesso gratuito (solo visione)
Dimensione
847.86 kB
Formato
Adobe PDF
|
847.86 kB | Adobe PDF | Visualizza/Apri |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.