A novel supramolecular cage built from the self-assembly of tris(2-pyridylmethyl)amine zinc complexes through imine condensation chemistry is reported. The cage recognition properties over a variety of structurally related guests, together with the kinetic study of the template assembly and disassembly, have been investigated in detail. This knowledge has been used to selectively modulate the rate of both assembly and disassembly processes. In particular, a novel disassembly method induced by strain release of the guest has been developed.

Triggering Assembly and Disassembly of a Supramolecular Cage

Badetti, Elena;Zonta, Cristiano
2017-01-01

Abstract

A novel supramolecular cage built from the self-assembly of tris(2-pyridylmethyl)amine zinc complexes through imine condensation chemistry is reported. The cage recognition properties over a variety of structurally related guests, together with the kinetic study of the template assembly and disassembly, have been investigated in detail. This knowledge has been used to selectively modulate the rate of both assembly and disassembly processes. In particular, a novel disassembly method induced by strain release of the guest has been developed.
File in questo prodotto:
File Dimensione Formato  
jacs 2017.pdf

non disponibili

Descrizione: full text
Tipologia: Versione dell'editore
Licenza: Accesso chiuso-personale
Dimensione 2.16 MB
Formato Adobe PDF
2.16 MB Adobe PDF   Visualizza/Apri
FullJACS1204.pdf

accesso aperto

Descrizione: full text post-print dell'autore
Tipologia: Documento in Post-print
Licenza: Accesso gratuito (solo visione)
Dimensione 847.86 kB
Formato Adobe PDF
847.86 kB Adobe PDF Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3702290
Citazioni
  • ???jsp.display-item.citation.pmc??? 12
  • Scopus 58
  • ???jsp.display-item.citation.isi??? 57
social impact