Acylation of ferrocene-catalyzed by scandium triflate was thoroughly investigated. Reaction time and temperature are important parameters, in that prolonged treatment causes substrate decomposition and/or catalyst deactivation. Hydrophobic alkylmethylimidazolium-based solvents gave best results, in particular 1-butyl-3-methylimidazolium bis(trifluorometansulfonyl) imide. Anhydrides behave as superior acylating reagents with respect to acyl chlorides. MW irradiation allowed to quantitatively acylate ferrocene within minutes. Â© 2008 Elsevier B.V. All rights reserved.
|Data di pubblicazione:||2008|
|Titolo:||Improvement of ferrocene acylation. Conventional vs. microwave heating for scandium-catalyzed reaction in alkylmethylimidazolium-based ionic liquids|
|Rivista:||JOURNAL OF ORGANOMETALLIC CHEMISTRY|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.jorganchem.2008.06.022|
|Appare nelle tipologie:||2.1 Articolo su rivista |