The selective oxidation of benzylic alcohols to carbonyl compounds, such as aldehydes and ketones, is a very important organic synthesis for industrial production and is one of the most challenging reactions in green chemistry. As a matter of fact, the aldehydes and ketones are key intermediates in perfumes, spices, flame retardants, pharmaceuticals and other fine chemicals. Although during past decades, a number of papers has been focused on developing new catalyst systems, for the selective oxidation of benzyl alcohols with mild, green, and economic process, it is still a big challenge in organic synthetic chemistry. In this study, a novel selective oxidation of benzyl alcohols to aldehydes and ketones was established by using H2O2 (30% aq) together with Pd(II)-based new catalysts.
Andrea Vavasori (Corresponding)
|Data di pubblicazione:||2017|
|Titolo:||A green selective oxidation of benzyl alcohol to benzaldehyde by using H2O2 and a Pd(II)-catalyst|
|Titolo del libro:||Book of Abstracts of 7th International IUPAC Conference on Green Chemistry|
|Appare nelle tipologie:||4.3 Poster in Atti di convegno|
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