The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6 to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2 at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C–N coupling

Allowing the direct interaction of: N -aryl α-diimines with a high valent metal chloride: One-pot WCl6-promoted formation of quinoxalinium salts

Bortoluzzi M.;
2017-01-01

Abstract

The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl6 to react with N-(2,6-diisopropylphenyl) α-diimines, in CH2Cl2 at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C–N coupling
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3694225
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