High catalytic activity of the PdCl2(PPh3)2âPPh3âAlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (â¤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6â93.8%.
Hydroethoxycarbonylation of α-Olefins at Low Pressure of Carbon(II) Oxide in the Presence of the PdCl2(PPh3)2–PPh3–AlCl3 System
VAVASORI, Andrea
2017
Abstract
High catalytic activity of the PdCl2(PPh3)2âPPh3âAlCl3 system containing AlCl3 as promotor has been demonstrated in the reaction of hydroethoxycarbonylation of hexene-1 and octene-1 at low pressure of carbon(II) oxide (â¤25 atm). The reaction yields linear and branched products. The optimal conditions of the process have been elaborated. The target products yield is 84.6â93.8%.
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