16 mol% Ta-doped ZrO2 powders were synthesized and densified by spark-plasma sintering (SPS) in vacuum, followed by post-SPS annealing in air, thus obtaining two ultrafine-grained ceramics consisting of Ta-doping stabilized orthorhombic ZrO2. The as-SPSed ceramic is black because it is actually a suboxide essentially with reduced cations and abundant oxygen vacancies, whereas the post-annealed ceramic is white because it is an oxide without vacancies and with only partially reduced cations. Both ceramics are relatively hard and brittle, but the as-SPSed ceramic was slightly more so, attributable to crystallographic and microstructural differences. Implications of interest for the ceramics community are discussed.
|Titolo:||Ceramics of Ta-doping stabilized orthorhombic ZrO2 densified by spark plasma sintering and the effect of post-annealing in air|
|Data di pubblicazione:||2017|
|Appare nelle tipologie:||2.1 Articolo su rivista |
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