Micellar media in water provide a simple and efficient environment to favor the double bond isomerization of terminal alkenes catalyzed by the cationic half-sandwich complex 1 at 95 °C. The micellar medium favors both catalyst dissolution in water by means of ion-pairing with the preferred anionic surfactants as well as substrate dissolution thus favoring its conversion into products.
Micellar promoted alkenes isomerization in water mediated by a cationic half-sandwich Ru(II) complex
SPERNI, Laura;SCARSO, Alessandro;STRUKUL, Giorgio
2017-01-01
Abstract
Micellar media in water provide a simple and efficient environment to favor the double bond isomerization of terminal alkenes catalyzed by the cationic half-sandwich complex 1 at 95 °C. The micellar medium favors both catalyst dissolution in water by means of ion-pairing with the preferred anionic surfactants as well as substrate dissolution thus favoring its conversion into products.
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