The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4]arene units. The capsule provides a combination of weak Brønsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction
The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4] arene units. The capsule provides a combination of weak Bronsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction.
Efficient epoxide isomerization within a self-assembled hexameric organic capsule
CANEVA, THOMAS;SPERNI, Laura;STRUKUL, Giorgio;SCARSO, Alessandro
2016-01-01
Abstract
The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4] arene units. The capsule provides a combination of weak Bronsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction.
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