New magnetically recoverable catalysts have been synthesized by deposition of 1% palladium (Pd)-metal on the polymer poly(1-oxo-trimethylene), containing 15% of magnetite. The magnetite allows the complete recovery of the catalyst with the simple application of an external magnetic field. The activity of such a catalyst has been studied under phosphine-free conditions in the alkoxycarbonylation of iodobenzene to the corresponding benzoic acid esters.
New magnetically recoverable catalysts have been synthesized by deposition of 1 % palladium (Pd)-metal on the polymer poly(1-oxo-trimethylene), containing 15 % of magnetite. The magnetite allows the complete recovery of the catalyst with the simple application of an external magnetic field. The activity of such a catalyst has been studied under phosphine-free conditions in the alkoxycarbonylation of iodobenzene to the corresponding benzoic acid esters.
Autori: | |
Data di pubblicazione: | 2016 |
Titolo: | New magnetically recoverable palladium-based catalysts active in the alkoxycarbonylation of iodobenzene |
Rivista: | PURE AND APPLIED CHEMISTRY |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1515/pac-2016-0204 |
Volume: | 88 |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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PAC 2016 pre referee.pdf | Versione pre-referaggio | Documento in Pre-print | Accesso chiuso-personale | Riservato |