The combination of a Bronsted acid catalyst and a supramolecular organic capsule formed by the self-assembly of six resorcin[ 4] arene units efficiently promotes the mild hydration of aromatic alkynes to their corresponding ketones. The capsule provides a suitable nanoenvironment that favors protonation of the substrate and addition of water.

Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule

LA SORELLA, GIORGIO;SPERNI, Laura;STRUKUL, Giorgio;SCARSO, Alessandro
2016-01-01

Abstract

The combination of a Bronsted acid catalyst and a supramolecular organic capsule formed by the self-assembly of six resorcin[ 4] arene units efficiently promotes the mild hydration of aromatic alkynes to their corresponding ketones. The capsule provides a suitable nanoenvironment that favors protonation of the substrate and addition of water.
2016
6
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/3676193
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