The crystal structure of the title compound, poly[di-4- formato-lead(II)], [Pb(HCOO)2]n, has been re-investigated. It consists of a three-dimensional polymeric network of Pb2+ nodes connected by bridging formate anions. Despite having been described previously, the structural information available so far [Harrison & Steel (1982). J. Organomet. Chem. 239, 105–113] is incomplete and the reported Pnma space group is incorrect. In this work, the space-group assignment to P212121 is discussed and a complete description of the structural features of lead(II) formate is provided.
Re-investigation of lead(II) formate
GAMBIRASI, ARIANNA;
2013-01-01
Abstract
The crystal structure of the title compound, poly[di-4- formato-lead(II)], [Pb(HCOO)2]n, has been re-investigated. It consists of a three-dimensional polymeric network of Pb2+ nodes connected by bridging formate anions. Despite having been described previously, the structural information available so far [Harrison & Steel (1982). J. Organomet. Chem. 239, 105–113] is incomplete and the reported Pnma space group is incorrect. In this work, the space-group assignment to P212121 is discussed and a complete description of the structural features of lead(II) formate is provided.
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