Encapsulation of a cationic carbodiimide condensing agent within a self-assembled hexameric capsule made of resorcin[4]arene units provides a nano-environment that efficiently steers the substrate selectivity in the amide synthesis reaction between carboxylic acids and primary amines. While in solution pairs of acids react similarly with a given amine, in the presence of the capsule the formation of the shorter amide is greatly favored.
Autori: | ||
Data di pubblicazione: | 2015 | |
Titolo: | Substrate selective amide coupling driven by encapsulation of a coupling agent within a self-assembled hexameric capsule | |
Rivista: | CHEMICAL COMMUNICATIONS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/c4cc08833f | |
Volume: | 51 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
File in questo prodotto:
File | Descrizione | Tipologia | Licenza | |
---|---|---|---|---|
authorreprintsChemCommun2015.pdf | Documento in Post-print | Accesso chiuso-personale | Riservato |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.