New soluble dyes and insoluble organic pigments based on the diketopyrrolopyrrole skeleton have been prepared via Suzuki-Miyaura coupling on 3,6-bis(4-bromophenyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione. Boc protection of the amidic functions was advantageously used to solubilize the starting diketopyrrolopyrrole prior to the introduction of substituents. Absorption, fluorescence emission and optical features of these new diketopyrrolopyrroles dyes are presented.
New 3,6-bis(biphenyl)diketopyrrolopyrrole dyes and pigments via Suzuki-Miyaura coupling
BENINATTO, RICCARDO;BORSATO, Giuseppe;DE LUCCHI, Ottorino;FABRIS, Fabrizio;LUCCHINI, Vittorio;ZENDRI, Elisabetta
2013-01-01
Abstract
New soluble dyes and insoluble organic pigments based on the diketopyrrolopyrrole skeleton have been prepared via Suzuki-Miyaura coupling on 3,6-bis(4-bromophenyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione. Boc protection of the amidic functions was advantageously used to solubilize the starting diketopyrrolopyrrole prior to the introduction of substituents. Absorption, fluorescence emission and optical features of these new diketopyrrolopyrroles dyes are presented.File in questo prodotto:
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