Hydrocarboxylation of propene in the presence of PdCl2(PPh3)2-PPh3, and BuOH gave PrCO2Bu with a high regioselectivity. The crystal structure of trans-Pd(COPr)Cl(PPh3)2, the active catalytic species in the reaction, is detd. The isolation of this active catalytic species support the reaction mechanism occurring via alkene insertion into a Pd-H bond.
Metals in organic syntheses. III. Highly regioselective propene hydrocarboxylation promoted by abistriphenylphosphinedichloropalladium-triphenylphosphine catalyst precursor: trans-Pd(COPr)Cl(PPh3)2 as an activecatalytic species
TONIOLO, Luigi
1979-01-01
Abstract
Hydrocarboxylation of propene in the presence of PdCl2(PPh3)2-PPh3, and BuOH gave PrCO2Bu with a high regioselectivity. The crystal structure of trans-Pd(COPr)Cl(PPh3)2, the active catalytic species in the reaction, is detd. The isolation of this active catalytic species support the reaction mechanism occurring via alkene insertion into a Pd-H bond.
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