The hydrido 1,3-di-p-tolyltriazenido complex of Pt(II), trans-[Pt(PPh3)2H(p-MeC6H4NN:NC6H4Me-p)] reacts with CO, 2,6-Me2C6H3NC, PPh3 and PhCCPh under mild conditions to yield Pt(0) complexes by reductive elimination of 1,3-ptolyltriazene.
Reductive elimination of 1,3-di-p-tolyltriazene in reactions of trans-hydrido-1,3-di-ptolyltriazenidobis(triphenylphosphine)platinum with carbon monoxide, 2,6-Me2C6H3NC, triphenylphosphine, and 1,1'-(1,2-ethynediyl)bisbenzene
TONIOLO, Luigi;
1977-01-01
Abstract
The hydrido 1,3-di-p-tolyltriazenido complex of Pt(II), trans-[Pt(PPh3)2H(p-MeC6H4NN:NC6H4Me-p)] reacts with CO, 2,6-Me2C6H3NC, PPh3 and PhCCPh under mild conditions to yield Pt(0) complexes by reductive elimination of 1,3-ptolyltriazene.
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