In the reaction with phenylacetylene leading to [(PPh3)2(CO)IrCl (HNNC6H4R-p)(CCPh)] (BF4) (R NO2, CN, COCH3), the vacant coordination site in [(PPh3)2 (CO)IrCl(N2C6H4 R-p)] (BF4) plays a key role in the activation of the acetylenic CH bond. ca]To whom correspondence should be addressed. © 1976.
A novel class of aryldiazene complexes: [(PPh3)2 (CO)IrCl(HNNC6H4R-p)(CCPh)] (BF4) (R = NO2, CN, COCH3)
TONIOLO, Luigi;
1976-01-01
Abstract
In the reaction with phenylacetylene leading to [(PPh3)2(CO)IrCl (HNNC6H4R-p)(CCPh)] (BF4) (R NO2, CN, COCH3), the vacant coordination site in [(PPh3)2 (CO)IrCl(N2C6H4 R-p)] (BF4) plays a key role in the activation of the acetylenic CH bond. ca]To whom correspondence should be addressed. © 1976.
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