The title compound [Pt(CCPh)(HNNC6H4F-p)(PPh3)2](BF4) has been synthesized from Pt(HCCPh)(PPh3)2 and p-FC6H4N2BF4, and a mechanism for its formation is proposed; X-ray diffraction studies show that the acetylide ligand is σ-bonded and that the PCCC system is essentially linear, while the diazene ligand has a trans configuration around the NN bond, and the hydrogen-bearing nitrogen atom is coordinated to the platinum. © 1975.
A novel synthesis and X-ray structure of a new aryldiazene complex: trans-(phenylacetylide)bis(triphenylphosphine)(p-fluorophenyldiazene)platinum(II) tetrafluoroborate
TONIOLO, Luigi;
1975-01-01
Abstract
The title compound [Pt(CCPh)(HNNC6H4F-p)(PPh3)2](BF4) has been synthesized from Pt(HCCPh)(PPh3)2 and p-FC6H4N2BF4, and a mechanism for its formation is proposed; X-ray diffraction studies show that the acetylide ligand is σ-bonded and that the PCCC system is essentially linear, while the diazene ligand has a trans configuration around the NN bond, and the hydrogen-bearing nitrogen atom is coordinated to the platinum. © 1975.
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