[Re(CO)3(PPh3)2Cl] reacts with Li(ArNXNAr) (X = CH, N; Ar = p-MeC6H4, Ph, p-ClC6H4, p-FC6H4) in boiling THF to yield [Re(CO)2(PPh3)2(ArNXNAr)]. The structure of these new complexes and the mode of coordination of the organo-N ligand are discussed on the basis of IR and 1H NMR spectra.

Synthesis and characterization of new formamidino and triazenido complexes of rhenium(I): [Re(CO)2(PPh3)2(ArNX-NAr)] (X = CH, N) [N-X resonating bonds)

TONIOLO, Luigi
1981-01-01

Abstract

[Re(CO)3(PPh3)2Cl] reacts with Li(ArNXNAr) (X = CH, N; Ar = p-MeC6H4, Ph, p-ClC6H4, p-FC6H4) in boiling THF to yield [Re(CO)2(PPh3)2(ArNXNAr)]. The structure of these new complexes and the mode of coordination of the organo-N ligand are discussed on the basis of IR and 1H NMR spectra.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/35357
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