The structure of the title compd. was detd. by x-ray crystallog. and refined by least-squares to R 0.032 using 2835 independent reflections. The orange crystals of the complex are monoclinic, space group C2/c, with a 22.121, b 19.190, c 10.111Å, and 92.77°; Z = 4. The triazenido ligand is unidentate and trans to the CO in this square-planar complex. Ir-N and Ir-C(carbonyl) bond lengths are 2.16 and 1.79Å, resp.
Aryltriazenido complexes. Crystal and molecular structure of trans-carbonyl(1,3-di-ptolyltriazenido)bis(triphenylphosphine)iridium(I)
TONIOLO, Luigi
1980-01-01
Abstract
The structure of the title compd. was detd. by x-ray crystallog. and refined by least-squares to R 0.032 using 2835 independent reflections. The orange crystals of the complex are monoclinic, space group C2/c, with a 22.121, b 19.190, c 10.111Å, and 92.77°; Z = 4. The triazenido ligand is unidentate and trans to the CO in this square-planar complex. Ir-N and Ir-C(carbonyl) bond lengths are 2.16 and 1.79Å, resp.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
