Aryldiazionium tetrafluoborates react with Rh(PPh3)2Cl(S), and [Rh(PPh3)2H2Cl(S)] under hydrogen, (S = solvent, to yield the same arylazorhodium complexes in both cases, and also hydrazine, amine, and ammonia derivatives in the latter. A discussion of the activation of the NN triple bond of the aryldiazonium cation is presented. © 1972.
The facile hydrogenation of the aryldiazonium functional group to hydrazine, amine, and ammonia derivatives
TONIOLO, Luigi
1972-01-01
Abstract
Aryldiazionium tetrafluoborates react with Rh(PPh3)2Cl(S), and [Rh(PPh3)2H2Cl(S)] under hydrogen, (S = solvent, to yield the same arylazorhodium complexes in both cases, and also hydrazine, amine, and ammonia derivatives in the latter. A discussion of the activation of the NN triple bond of the aryldiazonium cation is presented. © 1972.
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