Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(II) catalyst is released into solution where its catalytic activity is restored
Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(ii) catalyst is released into solution where its catalytic activity is restored. © 2012 Royal Society of Chemistry.
Switching the activity of a photoredox catalyst through reversible encapsulation and release
BIANCHINI, GIULIO;SCARSO, Alessandro;LA SORELLA, GIORGIO;STRUKUL, Giorgio
2012-01-01
Abstract
Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(ii) catalyst is released into solution where its catalytic activity is restored. © 2012 Royal Society of Chemistry.
| File | Dimensione | Formato | |
|---|---|---|---|
|
ReprintCHemCommun2012 good.pdf
non disponibili
Tipologia:
Documento in Post-print
Licenza:
Accesso chiuso-personale
Dimensione
756.32 kB
Formato
Adobe PDF
|
756.32 kB | Adobe PDF | Visualizza/Apri |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
