Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(II) catalyst is released into solution where its catalytic activity is restored

Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(ii) catalyst is released into solution where its catalytic activity is restored. © 2012 Royal Society of Chemistry.

Switching the activity of a photoredox catalyst through reversible encapsulation and release

BIANCHINI, GIULIO;SCARSO, Alessandro;LA SORELLA, GIORGIO;STRUKUL, Giorgio
2012

Abstract

Reversible encapsulation of [Ru(bpy)3]2+ within a self-assembled hexameric resorcin[4]arene capsule turns off the photocatalytic aerobic oxidation of an aliphatic sulfide. Upon addition of a competitive cationic guest, the Ru(II) catalyst is released into solution where its catalytic activity is restored
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/34947
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