Crystals of the title compd. are triclinic, space group P1, a 9.225(4), b 13.734(5), c 18.056(6) Å, 74.48(3), 94.40(3), 98.82(3)°; Z = 2; R = 0.084; T = 293 K. At. coordinates are given. A quasi regular square planar configuration is realized in the anion. The P-C bonds in the anion are significantly longer than the P-C(Ph) bonds in the cation. The C=O bond of 1.24 Å is clearly double.
Crystal structure of (cyclohexanonetriphenylphosphonium) trichloro(triphenylphosphine)palladate(II)-benzene (1/1),[(C6H5)3P(CHCH2CO(CH2)3)][(C6H5)3PPdCl3]•C6H6
TONIOLO, Luigi
2000-01-01
Abstract
Crystals of the title compd. are triclinic, space group P1, a 9.225(4), b 13.734(5), c 18.056(6) Å, 74.48(3), 94.40(3), 98.82(3)°; Z = 2; R = 0.084; T = 293 K. At. coordinates are given. A quasi regular square planar configuration is realized in the anion. The P-C bonds in the anion are significantly longer than the P-C(Ph) bonds in the cation. The C=O bond of 1.24 Å is clearly double.
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