The title complexes readily react with [ArN2]BF4 (Ar = p-MeC6H4, p-FC6H4) in C6H6-Me2CO or EtOH to yield [Ir(ArNN:NAr)(CO)(PPh3)2]BF4 and [Rh(CONArN:NAr)(N2Ar)(PPh3)2]BF4. The latter are formed by an insertion reaction. IR and NMR spectral date are discussed.

Reactivity of M(ArN-N=NAr)(CO)(PPh3)2 with aryldiazonium salts (M = rhodium(I), iridium(I); Ar = p-CH3C6H4, p-FC6H4)

TONIOLO, Luigi;
1979-01-01

Abstract

The title complexes readily react with [ArN2]BF4 (Ar = p-MeC6H4, p-FC6H4) in C6H6-Me2CO or EtOH to yield [Ir(ArNN:NAr)(CO)(PPh3)2]BF4 and [Rh(CONArN:NAr)(N2Ar)(PPh3)2]BF4. The latter are formed by an insertion reaction. IR and NMR spectral date are discussed.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/33041
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