The reactions of bromomalonaldehyde anion (BMA) with several metal(II) chlorides have been studied and the syntheses of the tris(chelate) AsPh4[Fe(BMA)3] complex and the complexes [M(BMA)2(H2O)2] and [M(BMA)2] (M FeII, CoII, NiII, CuII) are reported. Complexes CoBr2(CNR)4, [FeBr(CNR)5]BPh4 and [Cu(CNR)4]Br (R 4-CH3C6H4) were obtained by reaction of the BMA derivatives with RNC. © 1989.
Preparation and reactivity with isocyanide of bromomalonaldehyde complexes of iron, cobalt, nickel, and copper
ALBERTIN, Gabriele;BALDAN, Daniela;BORDIGNON, Emilio
1989-01-01
Abstract
The reactions of bromomalonaldehyde anion (BMA) with several metal(II) chlorides have been studied and the syntheses of the tris(chelate) AsPh4[Fe(BMA)3] complex and the complexes [M(BMA)2(H2O)2] and [M(BMA)2] (M FeII, CoII, NiII, CuII) are reported. Complexes CoBr2(CNR)4, [FeBr(CNR)5]BPh4 and [Cu(CNR)4]Br (R 4-CH3C6H4) were obtained by reaction of the BMA derivatives with RNC. © 1989.
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