The enantiopure C3-symmetric trioxime derived from (+)-syn-benzotricamphor forms a dimer in low-polar solvents which encapsulates small molecules, such as Ar, CO, O2, N2, and CH 4 (see picture; gray C, blue N, red O, white H). The two benzocyclotrimers are fastened together by six hydrogen bonds between the oxime moieties. Gas binding is fast on the NMR timescale at room temperature, but is slow and complete at lower temperature.
Gas Hosting in Enantiopure Self-Assembled Oximes
SCARSO, Alessandro;DE LUCCHI, Ottorino;FABRIS, Fabrizio
2007-01-01
Abstract
The enantiopure C3-symmetric trioxime derived from (+)-syn-benzotricamphor forms a dimer in low-polar solvents which encapsulates small molecules, such as Ar, CO, O2, N2, and CH 4 (see picture; gray C, blue N, red O, white H). The two benzocyclotrimers are fastened together by six hydrogen bonds between the oxime moieties. Gas binding is fast on the NMR timescale at room temperature, but is slow and complete at lower temperature.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
Angew. Chem. Int. Ed. 2007.pdf
non disponibili
Tipologia:
Documento in Post-print
Licenza:
Accesso chiuso-personale
Dimensione
171.45 kB
Formato
Adobe PDF
|
171.45 kB | Adobe PDF | Visualizza/Apri |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
