Significant substrate selectivity was observed in the competitive Heck coupling reaction, betweeniodoaryl substrates and five acrylate esters from methyl to lauryl with Pd(OAc)2in water, under cationicmicellar conditions. While in organic medium the shorter acrylate reacts faster than the longer ones,the opposite trend is observed in the micellar medium because the latter hosts the longer, lipophilicsubstrates much better than the shorter ones
Autori: | ||
Data di pubblicazione: | 2013 | |
Titolo: | Competitive micellar induced substrate selectivity in the Pd mediatedheck coupling between iodoaryl substrates and linear acrylic esters inwater | |
Rivista: | JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.molcata.2013.08.026 | |
Volume: | 379 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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