Significant substrate selectivity was observed in the competitive Heck coupling reaction, betweeniodoaryl substrates and five acrylate esters from methyl to lauryl with Pd(OAc)2in water, under cationicmicellar conditions. While in organic medium the shorter acrylate reacts faster than the longer ones,the opposite trend is observed in the micellar medium because the latter hosts the longer, lipophilicsubstrates much better than the shorter ones

Competitive micellar induced substrate selectivity in the Pd mediatedheck coupling between iodoaryl substrates and linear acrylic esters inwater

LA SORELLA, GIORGIO;SCARSO, Alessandro;STRUKUL, Giorgio
2013

Abstract

Significant substrate selectivity was observed in the competitive Heck coupling reaction, betweeniodoaryl substrates and five acrylate esters from methyl to lauryl with Pd(OAc)2in water, under cationicmicellar conditions. While in organic medium the shorter acrylate reacts faster than the longer ones,the opposite trend is observed in the micellar medium because the latter hosts the longer, lipophilicsubstrates much better than the shorter ones
File in questo prodotto:
File Dimensione Formato  
JMolCatA2013.pdf

non disponibili

Tipologia: Documento in Post-print
Licenza: Accesso chiuso-personale
Dimensione 824.93 kB
Formato Adobe PDF
824.93 kB Adobe PDF   Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/29564
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 6
  • ???jsp.display-item.citation.isi??? 6
social impact