Enantiopure (-)-5-oxoborneol was obtained in 35% overall yield in two steps, starting from readily available (-)-bornyl acetate and using oxone® as a safe and inexpensive oxidant. The reported procedure avoids the use of large excess of noxious chromium(VI), which was required by the so far reported syntheses.

A chromium-free synthesis of enantiopure 5-oxoborneol

TARTAGGIA, STEFANO;PADOVAN, Pierluigi;BORSATO, Giuseppe;DE LUCCHI, Ottorino;FABRIS, Fabrizio
2011-01-01

Abstract

Enantiopure (-)-5-oxoborneol was obtained in 35% overall yield in two steps, starting from readily available (-)-bornyl acetate and using oxone® as a safe and inexpensive oxidant. The reported procedure avoids the use of large excess of noxious chromium(VI), which was required by the so far reported syntheses.
2011
52
File in questo prodotto:
File Dimensione Formato  
TetLett2011.pdf

non disponibili

Tipologia: Documento in Post-print
Licenza: Accesso chiuso-personale
Dimensione 192.55 kB
Formato Adobe PDF
192.55 kB Adobe PDF   Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/10278/28908
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 3
  • ???jsp.display-item.citation.isi??? 3
social impact