The extreme lipophobicity of perfluorinated chains attached to amphiphilic thiolates triggers the formation of “stars” (or patches) surrounded by amphiphilic alkylthiolates in three-dimensional self-assembled monolayers. This strategy led to the first example of a water-soluble multicompartment monolayer wrapped around a gold core.
Formation of Patches on 3D SAMs Driven by Thiols with Immiscible Chains Observed by ESR Spectroscopy
POLIZZI, Stefano;
2009-01-01
Abstract
The extreme lipophobicity of perfluorinated chains attached to amphiphilic thiolates triggers the formation of “stars” (or patches) surrounded by amphiphilic alkylthiolates in three-dimensional self-assembled monolayers. This strategy led to the first example of a water-soluble multicompartment monolayer wrapped around a gold core.File in questo prodotto:
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