The title compounds form Diels-Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.
1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-Bromo-2-(p-tolylsulfinyl)ethyne: Versatile Reagents Eventually Leading to Benzocyclotrimers
DE LUCCHI, Ottorino;FABRIS, Fabrizio
2009-01-01
Abstract
The title compounds form Diels-Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.
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