The title compounds form Diels-Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.

1-Bromo-2-(diphenylphosphinoyl)ethyne and 1-Bromo-2-(p-tolylsulfinyl)ethyne: Versatile Reagents Eventually Leading to Benzocyclotrimers

DE LUCCHI, Ottorino;FABRIS, Fabrizio
2009

Abstract

The title compounds form Diels-Alder cycloadducts with a number of dienes, which can be transformed into vic-bromo(trimethylstannyl)olefins, ultimate precursors for the synthesis of benzocyclotrimers via copper-mediated cyclotrimerization. The overall result is a formal condensation of three diatomic carbons with three dienes.
File in questo prodotto:
File Dimensione Formato  
TetLett P-S.pdf

non disponibili

Tipologia: Documento in Post-print
Licenza: Accesso chiuso-personale
Dimensione 1.46 MB
Formato Adobe PDF
1.46 MB Adobe PDF   Visualizza/Apri

I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10278/26203
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 7
  • ???jsp.display-item.citation.isi??? 7
social impact