A novel method for the synthesis of new highly functionalized cyclotrimers is described. The method consists of an original synthesis of ‚-dibromosubstituted pyrroles, metalation, cycloaddition, and cyclotrimerization. The sequence is highly compatible with common functional groups and allows the construction of cup-shaped molecules functionalized both at the upper and bottom rim. This feature makes the newly formed structures useful scaffolds for the development of supramolecular receptors.
Autori: | ||
Data di pubblicazione: | 2005 | |
Titolo: | The Pyrrole Approach toward the Synthesis of Fully Functionalized Cup-Shaped Molecules | |
Rivista: | ORGANIC LETTERS | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1021/ol047569f | |
Volume: | 7 | |
Appare nelle tipologie: | 2.1 Articolo su rivista |
File in questo prodotto:
File | Descrizione | Tipologia | Licenza | |
---|---|---|---|---|
ol047569f.pdf | Documento in Post-print | Accesso chiuso-personale | Riservato |
I documenti in ARCA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.