In similarity with the strongly electrophilic BPSEs and despite its more electron-rich character, 1-phenylsul.nyl-2-phenylsulfanylethylene (SOSE) reacts with nucleophiles with displacement of the phenylthio moiety. Speci.cally it reacts with diols underbasic conditions to produce b-cycloacetalic sulfoxides. The reaction has been amply developed in carbohydrate chemistry.

Expeditious synthesis of beta-cycloacetalic sulfoxides. Introducing 1-phenylsulfinyl-2-phenylsulfanylethylene (SOSE), a promising new alkenylsulfur reagent

FABRIS, Fabrizio;DE LUCCHI, Ottorino;
2005

Abstract

In similarity with the strongly electrophilic BPSEs and despite its more electron-rich character, 1-phenylsul.nyl-2-phenylsulfanylethylene (SOSE) reacts with nucleophiles with displacement of the phenylthio moiety. Speci.cally it reacts with diols underbasic conditions to produce b-cycloacetalic sulfoxides. The reaction has been amply developed in carbohydrate chemistry.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/10278/22339
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