In similarity with the strongly electrophilic BPSEs and despite its more electron-rich character, 1-phenylsul.nyl-2-phenylsulfanylethylene (SOSE) reacts with nucleophiles with displacement of the phenylthio moiety. Speci.cally it reacts with diols underbasic conditions to produce b-cycloacetalic sulfoxides. The reaction has been amply developed in carbohydrate chemistry.
Autori: | |
Data di pubblicazione: | 2005 |
Titolo: | Expeditious synthesis of beta-cycloacetalic sulfoxides. Introducing 1-phenylsulfinyl-2-phenylsulfanylethylene (SOSE), a promising new alkenylsulfur reagent |
Rivista: | TETRAHEDRON LETTERS |
Volume: | 46 |
Appare nelle tipologie: | 2.1 Articolo su rivista |
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TetLett_SOSE.pdf | Documento in Post-print | Accesso chiuso-personale | Riservato |
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